Depends what sort of job or course it is for!
If its a job you should start with relevant work history, if its a course of study start with relevant qualifications and experience.
Then you should have a "job specific skills" section (or "subject specific skills" for a course of study) with bullet points and an explanatory sentence about each skill, and a "transferable skills" section where you list IT skills, team working, communication, etc.
What are you applying for? Its always important to tailor the CV to the opportunity!