Those weights can't be right unless they are tiny babies! Maybe try centering the scale and make sure they are putting all their weight on it (it can be hard to get them to stand balanced on a food scale, I use one to weigh my pigs too and it can be finicky!)
In any event, a checkup is probably a good idea since they are new to your home and you don't know the full history. They can check the female for potential pregnancy and look at the health of the two boys, including the thinner one. I'm also from Ontario (hi fellow Canadian!) and most vets who are knowledgeable about guinea pigs will bill themselves as seeing 'exotics' or 'pocket pets.' It's definitely worth seeing one of these vets, the cost is about the same and their knowledge base is a lot better, they will catch some things that a vet who doesn't specialize in rodents/exotics might not see.
For the thin boy, make sure the vet takes a good look at his teeth, the molars and not just the incisiors in the front. Teeth would be an obvious thing to check for weight loss, and sometimes the teeth in the front can look normal while the teeth in the back are overgrown.
All the best with your new pigs and I hope the vet can give you some feedback to get your little guy back on track weight-wise!