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A new environment will cause them to go into a period of reestablishing their relationship and during this time you do see increased dominance. If two piggies are compatible, then things will not escalate beyond normal mounting and rumbling. They will settle back down in a few days and everything will be ok.
If they are not compatible, and were never compatible, then the move can make those incompatibilities come to light even more so. If if looks like things aren’t good between them, then you don’t need to wait for them to fight to call it a day on their relationship.
However, what you cannot do is just separate for them for the night and put them back together and separate again. This amount of separation and reintroduction causes stress to them both and will further destabilise the relationship.
If you carry out a trial separation to test their bond then it is a one time event. You separate, and see how the underpig behaves (the dominance will always be upset by a separation so it’s not that ones reaction you watch). If the underpig perks up when separated then it is likely the bond is broken and they should not be put back together. If you feel you can try a reintroduction, then it must be done just once and always on neutral territory (you cannot just put a piggy back into the cage of the other piggy, or just remove a divider) . The answer will then come almost straight away upon reintroduction - if things escalate almost straight away then their relationship is over and they need to be permanently separated and not be put back together again.
While having a large cage (180x60cm is recommended for a boar pair) means they can have territory each, multiple items etc means they have no reason to argue it isn’t the be all and end all. If they simply aren’t compatible, don’t like each other and clear bullying is occurring, then nothing is going to change that and the only option is sadly to permanently separate them.
They can live in separate but side by side cages as neighbours permanently. This will enable interaction through the bars only so they don’t get lonely.
If you choose to give one up, then surrendering to a rescue centre is best. They will ensure that piggy is bonded with another and rehomed properly.
You will then need to find a suitable character compatible companion for the piggy you keep. Again, this is best done via the assistance of a rescue centre if possible. If you don’t have an option for this kind of rescue dating and need to bring home a piggy on spec (from a pet shop for example), then again there is a risk that the two won’t be compatible and you would still need to have a plan b in case any bonding with a new piggy failed and they too have to live in separate cages.
The guides below explain further
A Comprehensive Guide to Guinea Pig Boars
Bonds In Trouble
Bonding and Interaction: Illustrated social behaviours and bonding dynamics
Boars: Teenage, Bullying, Fighting, Fall-outs And What Next?
Dominance Behaviours In Guinea Pigs